Chapter 5
Mixtures: Simple, Ideal, Real
5.1
Classification
5.2
Caloric properties of ideal-gas mixtures
5.3
Thought experiment: Gibbs paradox
5.4
What is the most entropic ideal-gas binary mixture?
5.5
Extensive properties of mixtures: Volume of mixtures and partial molar volume
5.6
Example for negative partial molar volume: salt + water
5.7
Gibbs-Duhem equation
5.7.1
Application of Gibbs-Duhem: rationalization of phi/x-curves
5.8
Excess functions
5.9
Phase separation
5.10
Activity of solutions of condensed systems (liquid, solid)
5.11
Raoult and Henry law for activity and fugacity
5.12
Activities of regular solutions
5.13
Colligative properties of ideal systems
5.14
Colligative properties - osmosis
5.15
Quantification of osmosis (ideal systems): Van’t Hoff equation
5.16
Stability and infinitesimal fluctuations
© J. Carstensen (TD Kin I)
