Chapter 4
Gibbs phase rule and pure substances

4.1 Gibbs phase rule - general discussion
4.2 Gibbs phase rule including chemical reactions and other restraints
4.2.1 Examples: Errors in binary phase diagrams
4.3 Equilibrium conditions for pure substances and second law
4.4 p,V,T surface for pure substance
4.5 Clapeyron’s equation and application to melting
4.6 Clapeyron’s equation and application to vaporization
4.7 Clapeyron’s equation and application to sublimation
4.7.1 Examples for solid-solid equilibria
4.8 Ehrenfest classification of phase transitions

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© J. Carstensen (TD Kin I)