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Bulk Si solar cells are made from (cheap) single crystalline wafers (cut
squarish) or from square multicrystalline (mc) wafers. They account for about 85 % of the installed solar power at present (2008).
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Processing Time |
1s / solar cell |
Cost Decrease | 5 % / a |
Efficiency Increase | 20 % in 2012 ? |
Key Material Supply | 30 % /a more Si |
Industry Growth Rates > 30 % for many years |
Supply capital and people |
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A yearly production of 1 GWpeak means about 107
m2=10 km2 pn-junction of good quality and much more |
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Consider Þ |
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A big problem is cranking up world wide Si production by 30 % - 40 %
per year. | |
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mc wafers are produced by Si casting. Problems are |
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Expansion upon crystallization. |
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Reaction with walls of mold | |
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Columnar grain growth required |
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300 kg ingots are routinely cast in 2007; liquid encapsulation and precise temperature
control are essential | |
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Sawing the ingot into mc-Si wafers with as little losses as possible and
with wafer thicknesses of < 300 µm, while straight-forward, is "high-tech". |
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Saw damage is removed by a chemical etch. |
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Processing, simple in principle, has to meet the conditions above and is highly
specialized. Essential processes are: | |
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Diffusion, edge isolation, passivation, screen printing contacts and sintering contacts. |
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Essential device features are back surface field, gettering of impurity atoms, H-passivation
of grain boundaries and other defects. | |
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© H. Föll (Semiconductor Technology - Script)