8.2.3 Summary to: 8.2 Making Bulk Si Solar Cells

Bulk Si solar cells are made from (cheap) single crystalline wafers (cut squarish) or from square multicrystalline (mc) wafers. They account for about 85 % of the installed solar power at present (2008).
Processing Time 1s / solar cell
Cost Decrease 5 % / a
Efficiency Increase 20 % in 2012 ?
Key Material Supply 30 % /a more Si
Industry Growth Rates
> 30 % for many years
Supply capital and people
A yearly production of 1 GWpeak means about 107 m2=10 km2 pn-junction of good quality and much more
Consider Þ  
A big problem is cranking up world wide Si production by 30 % - 40 % per year.  
     
mc wafers are produced by Si casting. Problems are  
Casting of Si for solar cells
Expansion upon crystallization.  
Reaction with walls of mold  
Columnar grain growth required  
300 kg ingots are routinely cast in 2007; liquid encapsulation and precise temperature control are essential  
Sawing the ingot into mc-Si wafers with as little losses as possible and with wafer thicknesses of < 300 µm, while straight-forward, is "high-tech".  
Saw damage is removed by a chemical etch.  
         
Processing, simple in principle, has to meet the conditions above and is highly specialized. Essential processes are:  
Solar cell processing
Diffusion, edge isolation, passivation, screen printing contacts and sintering contacts.  
Essential device features are back surface field, gettering of impurity atoms, H-passivation of grain boundaries and other defects.  
   
Exercise 8.2-1
Summing up Class Exercises

With frame Back Forward as PDF

© H. Föll (Semiconductor Technology - Script)