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How large will be the distance d between the (center of gravity)
of the positive and negative charges for reasonable field strengths and atomic numbers, e.g. the combinations of
- 1 kV/cm
- 100 kV/cm
- 10 MV/cm
- , the last one being about the ultimate limit for the best dielectrics there are,
- z
= 1 (H, Hydrogen)
- z = 50 (Sn (= tin), ...)
- z = 100 (?)
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From the backbone we have a relation for d as a function of z,m
the radius R of the atom, and the field strength E: |
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We need to look up some number for the radius of the three atoms given (try this
link), then the calculation is straight forward - let's make a table: |
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Atom | R |
d(1 kV/cm) | d(100 kV/cm) |
d(10 MV/cm) | z = 1 |
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| z = 50 |
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| z = 100 |
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Compared to the radius of the atoms, the separation distance is tiny. No wonder, electronic
polarization is a small effect with spherical atoms! |
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Calculate the "spring constant" and from that the resonance
frequency of the "electron cloud" (assume the nucleus to be fixed in space). |
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If you don't know off-hand the resonance frequency of a simple harmonic oscillator
- that's fine. If you don't know exactly what that is, and where you can look it up - you are in deep trouble. |
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Anyway, in this link you get all you need. In particular
the resonance (circle) frequency w0 of a harmonic oscillator with the mass
m and the spring constant kS is given by |
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w0 | = |
æ ç è |
kS m |
ö ÷ ø |
1/2 |
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How large are the spring constants? That is question already answered in the backbone, so we import the
equation |
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kS = |
æ ç è |
(ze) 2
4 pe0 · R
3 |
ö ÷ ø |
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Again, let's make a table for the answers: |
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Atom | Spring constant |
w0 |
z = 1 | | |
z = 50 | | |
z = 100 | |
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© H. Föll (Electronic Materials - Script)