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HyperscriptDefects in Crystals© H. Föll Contents |
Hyperscripts of AMAT: General Information Index |
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1.1 Scope of the Course | ||
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General outline, Relation to other courses: | ||
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Required background knowledge | ||
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Organizational remarks | ||
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1.2 Topics for Seminar | ||
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Suggested Topics for Seminar | ||
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Rules for seminar | ||
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1.3 General Classification and Properties of Defects | ||
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Classification of defects | ||
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Materials properties and defects | ||
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The larger view and complications |
2. Properties of Point Defects
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2.1 Intrinsic Point Defects and Equilibrium | ||
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Single vacancies and interstitials | ||
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Frenkel and Schottky defects | ||
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Mixed point defects | ||
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2.2 Extrinsic Point Defects and Agglomerates | ||
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Impurity atoms; interaction with intrinsic defects | ||
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Global and local equilibrium, agglomeration | ||
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2.3 Point Defects in Semiconductors like Silicon | ||
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The special status of Silicon with respect to point defects and diffusion | ||
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2.4 Point Defects in Ionic Crystals | ||
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Differences in notations, the role of the chemical potential | ||
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Working with the different notation, examples |
3. Point Defects and Diffusion
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3.1 General Remarks | ||
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Ficks laws, relation between phenomenological view and atomic view | ||
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Technological relevance and open questions | ||
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3.2 Atomic Mechanisms of Diffusion | ||
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Vacancy and interstitial mechanisms, kick-out and exotic mechanisms | ||
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Self diffusion | ||
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Impurity diffusion | ||
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3.3 Experimental Approach to Diffusion Phenomena | ||
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Review of methods | ||
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Tracer methods | ||
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Working with the different notation, examples |
4. Experimental Techniques for Studying Point Defects
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4.1 Equilibrium Techniques | ||
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Differential volume expansion | ||
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Positron annihilation | ||
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Some other methods | ||
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4.2 Non-Equilibrium Techniques | ||
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Quenching and related methods | ||
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Some specialities | ||
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Specialties | ||
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Ionic crystals and special methods |
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5.1 Basics of Dislocations Crystals | ||
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Burgers- and line vectors. | ||
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Volterra definition of dislocations | ||
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5.2 Elasticity Theory, Energy and Forces | ||
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Elasticity theory of dislocations | ||
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Energies, forces, interactions | ||
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5.3 Movement of Dislocations | ||
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Basics, Peierls potential, kinks and jogs | ||
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Climb processes, interaction with point defects | ||
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5.4 Partial Dislocations and Stacking Faults | ||
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Energy consideration, partial dislocations in fcc crystals | ||
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Stacking faults and point defects | ||
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5.5 Dislocations and Plastic Deformation | ||
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Some general considerations, theory of hardening | ||
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Some specifics for important lattices and materials |
6. Observation of Dislocations
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6.1 Decoration and Microscopy | ||
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Preferential etching | ||
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IR - microscopy and others | ||
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6.2 X-ray Topography | ||
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Principle and examples | ||
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6.3 Transmission Electron Microscopy | ||
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Basics and contrast conditions | ||
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Possibilities and limitations |
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7.1 Coincidence Lattice. O-lattice and DSC lattice for grain Boundaries | ||
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Twin boundaries to get the idea | ||
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The coincidence lattice and the O-lattice | ||
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The DSC-lattice and grain boundary dislocations | ||
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7.2 Case Studies | ||
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Tilt boundaries | ||
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Twist boundaries | ||
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Complicated Boundaries | ||
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7.3 Bollmanns O-Lattice Theory | ||
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Basic Concept | ||
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Working with the O-Lattice | ||
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The Significance of the O-Lattice |
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8.1 Generalization of the O-lattice model | ||
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Misfit dislocations | ||
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a more general view | ||
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8.2 Case studies | ||
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Pd2Si as a simple model of a phase boundary | ||
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The Ni - Si systems and its intricacies | ||
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8.3 Steps in Interfaces | ||
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The Relation Between Steps and Dislocations in S=3 Boundaries | ||
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Open Questions |