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HyperscriptDefects in Crystals© H. Föll Contents |
Hyperscripts of AMAT: General Information Index |
1.1 Scope of the Course | |||
General outline, Relation to other courses: | |||
Required background knowledge | |||
Organizational remarks | |||
1.2 Topics for Seminar | |||
Suggested Topics for Seminar | |||
Rules for seminar | |||
1.3 General Classification and Properties of Defects | |||
Classification of defects | |||
Materials properties and defects | |||
The larger view and complications |
2. Properties of Point Defects
2.1 Intrinsic Point Defects and Equilibrium | |||
Single vacancies and interstitials | |||
Frenkel and Schottky defects | |||
Mixed point defects | |||
2.2 Extrinsic Point Defects and Agglomerates | |||
Impurity atoms; interaction with intrinsic defects | |||
Global and local equilibrium, agglomeration | |||
2.3 Point Defects in Semiconductors like Silicon | |||
The special status of Silicon with respect to point defects and diffusion | |||
2.4 Point Defects in Ionic Crystals | |||
Differences in notations, the role of the chemical potential | |||
Working with the different notation, examples |
3. Point Defects and Diffusion
3.1 General Remarks | |||
Ficks laws, relation between phenomenological view and atomic view | |||
Technological relevance and open questions | |||
3.2 Atomic Mechanisms of Diffusion | |||
Vacancy and interstitial mechanisms, kick-out and exotic mechanisms | |||
Self diffusion | |||
Impurity diffusion | |||
3.3 Experimental Approach to Diffusion Phenomena | |||
Review of methods | |||
Tracer methods | |||
Working with the different notation, examples |
4. Experimental Techniques for Studying Point Defects
4.1 Equilibrium Techniques | |||
Differential volume expansion | |||
Positron annihilation | |||
Some other methods | |||
4.2 Non-Equilibrium Techniques | |||
Quenching and related methods | |||
Some specialities | |||
Specialties | |||
Ionic crystals and special methods |
5.1 Basics of Dislocations Crystals | |||
Burgers- and line vectors. | |||
Volterra definition of dislocations | |||
5.2 Elasticity Theory, Energy and Forces | |||
Elasticity theory of dislocations | |||
Energies, forces, interactions | |||
5.3 Movement of Dislocations | |||
Basics, Peierls potential, kinks and jogs | |||
Climb processes, interaction with point defects | |||
5.4 Partial Dislocations and Stacking Faults | |||
Energy consideration, partial dislocations in fcc crystals | |||
Stacking faults and point defects | |||
5.5 Dislocations and Plastic Deformation | |||
Some general considerations, theory of hardening | |||
Some specifics for important lattices and materials |
6. Observation of Dislocations
6.1 Decoration and Microscopy | |||
Preferential etching | |||
IR - microscopy and others | |||
6.2 X-ray Topography | |||
Principle and examples | |||
6.3 Transmission Electron Microscopy | |||
Basics and contrast conditions | |||
Possibilities and limitations |
7.1 Coincidence Lattice. O-lattice and DSC lattice for grain Boundaries | |||
Twin boundaries to get the idea | |||
The coincidence lattice and the O-lattice | |||
The DSC-lattice and grain boundary dislocations | |||
7.2 Case Studies | |||
Tilt boundaries | |||
Twist boundaries | |||
Complicated Boundaries | |||
7.3 Bollmanns O-Lattice Theory | |||
Basic Concept | |||
Working with the O-Lattice | |||
The Significance of the O-Lattice |
8.1 Generalization of the O-lattice model | |||
Misfit dislocations | |||
a more general view | |||
8.2 Case studies | |||
Pd2Si as a simple model of a phase boundary | |||
The Ni - Si systems and its intricacies | |||
8.3 Steps in Interfaces | |||
The Relation Between Steps and Dislocations in S=3 Boundaries | |||
Open Questions |