2.1 Basic Notation: System and state

In thermodynamics (and in nearly all other branches of natural science) the part on which the focus of interest lies is called the system. The remaining is called the surrounding, i.e.
universe = system + surrounding
The astonishing fact about thermodynamics is that all measurements of properties and changes of the system are measured in the surrounding. The separation is important for many practical purposes: e.g. the entropy of a system can decrease, but the entropy of the universe can only increase (2nd Law).
Several kinds of systems exist:

Within the system ”phases” exist. A phase is a chemically homogeneous body on a macroscopic scale. No discontinuous changes of states are possible within a phase. Within a multi-phase material (composite) properties can change discontinuously at the phase boundary.


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© J. Carstensen (TD Kin I)