3.4.4 Summary to: 3.4 Structure, Interface and Some Properties

Epitaxial layers are crucial for semiconductor technology.
Misfit dislocations
Misfit of lattice constants will produce strained layers upon epitaxial growth; strain relief happens by the formation of misfit dislocations.
Misfit dislocatipons must be avoided at all costs!  
Below a usually rather small critical thickness dcrit of the the thin layer no misfit dislocations will occur.  
Rule of thumb:
0.5 % misfit   Þ dcrit »10 nm
   
     
The internal structure of thin films can be anything known from bulk materials plus some (important!) specialities.  
a-Si: Micro electronics
a-Si:H: Solar cells, LCD displays
µc-Si:H: Solar cells
       
Properties of thin films can be quite different from that of the bulk material  
Much better in thin films
  • Electrical break-down field strength of dielectrics.
  • Critical current densities in conductors.
The reason can be differences in length scales.  
Semiconductor technology relies to some extent on superior thin film properties  
Exercise 3.4-1
All Questions to 3.4

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© H. Föll (Semiconductor Technology - Script)