5.1 One electron approximation

we will have a closer look on a many particle system in which the one electron approximation is allowed, i.e. 

All perturbations from outside

Electrons will be scattered into mixed states ψ=ncnfn

The dominant and most fundamental perturbation of all systems is the temperature; e.g. the Brownian motion of the particles will excite electrons leading to a constant interaction between electrons. There exists a continuous flux of electrons into neighboring states. This flux is defined by |cn|2, i.e. the mixture of pure states. The coefficients |cn|2 are calculated from the matrix elements

 fm|Perturbation|fn(5.1)


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© J. Carstensen (Quantum Mech.)